DOW ELANCO, A JOINT VENTURE -- GARLON 4 HERBICIDE #38322  -- 6840-01-328-4042
<pre>=====================  Product Identification  =====================

Product ID:GARLON 4 HERBICIDE #38322
MSDS Date:04/29/1994
FSC:6840
NIIN:01-328-4042
=== Responsible Party ===
Company Name:DOW ELANCO, A JOINT VENTURE
Address:9002 PURDUE ROAD, QUAD IV
City:INDIANAPLOIS
State:IN
ZIP:46268-1189
Country:US
Info Phone Num:800-352-6777
Emergency Phone Num:517-636-4400
CAGE:0TNR0
=== Contractor Identification ===
Company Name:ARBORCHEM PRODUCTS CO
Address:708 BLAIL MILL RD
Box:City:WILLOW GROVE
State:PA
ZIP:19090
Country:US
Phone:215-659-7922
CAGE:76415
Company Name:CORNBELT CHEMICAL COMPANY
Address:1515 MOCKINGBIRD AVENUE
Box:City:MCCOOK
State:NE
ZIP:69001
Phone:(800) 652-9306
CAGE:0AGD9
Company Name:DOW ELANCO
Address:QUAD IV, 9002 PURDUE RD
Box:City:INDIANAPOLIS
State:IN
ZIP:46268-1189
Country:US
Phone:517-636-4400
CAGE:0TNR0
Company Name:KOPPERS ROOFING SERVICES
Address:436 7TH AVE
Box:City:PITTSBURGH
State:PA
ZIP:15219
Country:US
Phone:412-227-2884
CAGE:0EGB7
Company Name:TIMBERLAND ENTERPRISES INC
Address:140 ARKANSAS ST
Box:557
City:MONTICELLO
State:AR
ZIP:71655
Country:US
Phone:501-367-8561
CAGE:1HB45

=============  Composition/Information on Ingredients  =============

Ingred Name:KEROSENE AND PROPRIETARY INGREDIENTS
CAS:8008-20-6
RTECS #:OA5500000
Fraction by Wt: 38.4%
Other REC Limits:10MG/M3
OSHA PEL:100 PPM
ACGIH TLV:100 PPM 9091

Ingred Name:TRICLOPYR ((3,5,6-TRICHLORO-2-PYRIDINYL)OXY) ACETIC ACID,
    BUTOXY ETHYL ESTER
CAS:64700-56-7
RTECS #:AJ8970000
Fraction by Wt: 61.6%
Other REC Limits:NONE RECOMMENDED

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50 RABBIT SKIN = >2000 MG/KG*
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:EYES: MAY CAUSE SLIGHT TRANSIENT IRRIT
    SKIN: CHRONIC MAY CAUSE SKIN IRRIT/ALERGIC REACTIONS IN SOME
    PEOPLE/UNDILUTED. SKIN ACUTE UNLIKELY/CHRONIC/MAY RESULT IN
    ABSORPTION OF HARMFUL AMOUNTS. INGESTION : SMALL AMOUNTS SWALLOWED
    IN NORMAL HANDLING NOT LIKE TO CAUSE INJURY. LARGE AMOUNTS MAY
    CAUSE INJURY. **
Explanation of Carcinogenicity:NK  *ORAL LD50 MALE RATS = 1581 MG/KG,
    FEMALE RATS 1338 MG/KG.
Effects of Overexposure:EXCESSIVE EXPOSURE MAY CAUSE CENTRAL NERVOUS
    SYSTEM AFFECTS DUE TO KEROSENE. TARGET ORGANS REPEATED EXCESSIVE
    EXPOSURE MAY CAUSE LIVER/KIDNEY/BLOOD AFFECTS/BIRTH DEFECTS ARE
    UNLIKELY. **IF ASPIRATED/M AY CAUSE LUNG DAMAGE OR DEATH DUE TO
    CHEM PNEUMONIA ***
Medical Cond Aggravated by Exposure:NK ***INHALATION: EXCESSIVE
    EXPOSURE MAY CAUSE IRRIT TO UPPER RESPIRATORY TRACT.

=======================  First Aid Measures  =======================

First Aid:EYES: FLUSH W/PLENTY OF WATER. SKIN: WASH W/FLOWING WATER OR
    SHOWER/CALL DR IF IRRIT PERSISTS. INGESTION: DO NOT INDUCE
    VOMITING. CALL DR. &/OR TRANSPORT TO EMERG. FACILITY IMMEDIATELY.
    INHALATION:GET  FRESH AIR. IF EFFECTS OCCUR CALL DR. ****

=====================  Fire Fighting Measures  =====================

Flash Point Method:TCC
Flash Point:147F,64C
Lower Limits:NOT EST.
Upper Limits:NOT EST.
Extinguishing Media:WATER FOG, FOAM, CO2, DRY CHEM.
Fire Fighting Procedures:USE POSITIVE PRESSURE SCBA & FULL PROTECTIVE
    CLOTHING.
Unusual Fire/Explosion Hazard:COMBUSTIBLE. TOXIC IRRITATING VAPORS MAY
    BE PRODUCED IF PRODUCT INVOLVED IN FIRE.

==================  Accidental Release Measures  ==================

Spill Release Procedures:DIKE LARGE SPILLS/KEEP OUT OF STREAMS AND
    DOMESTIC WATER SUPPLY/ABSORB SMALL SPILLS IN INERT ABSORBENT
    MATL/SAND.

======================	Handling and Storage  ======================

Handling and Storage Precautions:KEEP AWAY FROM CHILDREN. DO NOT USE
    NEAR HEAT, OPEN FLAME. AVOID CONTACT W/EYES/SKIN/CLOTHING.
Other Precautions:DO NOT SHIP/STORE W/FOOD/FEED/DRUGS/CLOTHING. DO NOT
    CONTAM WATER/FOOD/FEED BY STORAGE/DISPOSAL.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW
    THE EXPOSURE GUIDELINE. WHEN RESPIRATORY PROTECTION IS REQUIRED FOR
    CERTAIN OPERATIONS USE AN APPROVED AIR PURIFYING RESPIRATOR.
Ventilation:PROVIDE GENERAL &/OR LOCAL EXHAUST VENTILATION TO CONTROL
    AIRBORN LEVELS BELOW EXPOSURE GUIDELINES.
Protective Gloves:IMPERVIOUS MATL.
Eye Protection:SAFETY GLASSES.
Supplemental Safety and Health
DISTRIBUTOR: RED RIVER SPECIALTIES; CAGE 0FHX3. ****DR NOTE: DR SHOULD
    MAKE DECISION TO INDUCE VOMITING.IF PERFORM LAVAGE,
    ENDOTRACHEAL/ESOPHOGEAL CONTROL.WEIGH DANGER ASPIRATION AGAINST
    TOXICITY WHEN  CONSIDERING EMPTYING STOMACH.NO ANTEDOTE.SUPPORT
    CARE.TREATMENT UP TO DR'S RESPONSE TO PATIENT REACTION. (INFO ON
    FILE)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:>302F,>150C
Vapor Pres:0.1 /37.8C
Vapor Density:>1.0
Spec Gravity:1.08
Solubility in Water:EMULSIFIES.
Appearance and Odor:AMBER LIQUID, ODOR NOT AVAILABLE

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
ACID, BASE & OXIDIZING MATLS.
Stability Condition to Avoid:AVOID SOURCES OF IGNITION IF TEMP IS
    >FLASH POINT.
Hazardous Decomposition Products:NITROGEN OXIDES/HYDROGEN CHLORIDE &
    PHOSGENE MAY RESULT UNDER FIRE CONDITIONS.

====================  Disposal Considerations  ====================

Waste Disposal Methods:PESTICIDE, SPRAY MIXTURE OR RINSE WATER THAT
    CAN'T BE USED ACCORDING TO LABEL INSTRUCTIONS MUST BE DISPOSED OF
    ACCORDING TO APPLICABLE FEDERAL, STATE, LOCAL PROCEDURES.

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