EASTMAN KODAK CO -- 146 4817, CONC, KODAK DEVELOPER D-76 -- 6750-01-353-6581
===================== Product Identification ===================== Product ID:146 4817, CONC, KODAK DEVELOPER D-76 MSDS Date:02/22/2001 FSC:6750 NIIN:01-353-6581 === Responsible Party === Company Name:EASTMAN KODAK CO Address:343 STATE ST City:ROCHESTER State:NY ZIP:14650-1115 Country:US Info Phone Num:800-242-2424 Emergency Phone Num:716-722-5151/716-724-4501 Preparer's Name:NOT PROVIDED CAGE:19139 === Contractor Identification === Company Name:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS Address:343 STATE ST Box:City:ROCHESTER State:NY ZIP:14650-1115 Country:US Phone:716-722-5151/(800) 242-2424 Contract Num:SP0500-96-D-9413-N782 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Minumum % Wt:85. Maxumum % Wt:90. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:NOT PROVIDED Ingred Name:HYDROQUINONE CAS:123-31-9 RTECS #:MX3500000 = Wt:4. Other REC Limits:NOT PROVIDED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SODIUM TETRABORATE, PENTAHYDRATE CAS:1330-43-4 RTECS #:VZ2275000 Minumum % Wt:1. Maxumum % Wt:5. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:1 MG/M3 Ingred Name:4-(METHYLAMINO)PHENOL SULFATE CAS:55-55-0 RTECS #:SL8650000 Minumum % Wt:1. Maxumum % Wt:5. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:NOT PROVIDED Ingred Name:BORIC ANHYDRIDE CAS:1303-86-2 RTECS #:ED7900000 < Wt:1. Other REC Limits:NOT PROVIDED OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT PROVIDED Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION: HARMFUL IF INHALED. AIRBORNE DUST IRRITATING. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES BURNS. AIRBORNE DUST IRRITATING. SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SK IN REACTION BASED ON HUMAN EXPERIENCE. MAY CAUSE SKIN DEPIGMENTATION. INGESTION: HARMFUL IF SWALLOWED. MAY CAUSE BURNS OF GASTROINTESTINAL TRACT IF SWALLOWED. Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION (COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NON E - NATIONAL TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE Effects of Overexposure:INHALATION: AIRBORNE DUST IRRITATING. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO THE RESPIRATORY TRACT. EYES: CAUSES BURNS . AIRBORNE DUST IRRITATING. SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION BASED ON HUMAN EXPERIENCE. MAY CAUSE SKIN DEPIGMENTATION. INGESTION: MAY CAUSE BURNS OF GASTROINTESTINAL TRACT IF SWALLOWED. Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING, WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA. ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IMME DIATELY. SKIN: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES, REMOVING CONTAMINATED CLOTHING AND SHOES. IF SKIN IRRITATION OR ALLERGIC SKIN REACTION DEVELOPS, GET MEDICAL ATTENTION. WASH CONTA MINATED CLOTHING BEFORE REUSE. INGESTION: ONLY INDUCE VOMITING AT THE INSTRUCTION OF MEDICAL PERSONNEL. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTHTO AN UNCONSC IOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNT OF WATER. OTHERWISE, SWEEP UP AND PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCE. Other Precautions:AVOID BREATHING DUST. DO NOT GET IN EYES AND AVOID CONTACT WITH SKIN AND CLOTHING. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: DUST. A RESPIRATOR SHOULD BE WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE BEEN RELEASED. RESPIRATOR TYPE: ACID GAS. ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation:USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING APPROPRIATE FOR RISK OF EXPOSURE Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES) AND FACE SHIELD. Other Protective Equipment:WEAR A FULL-FACE RESPIRATOR, IF NEEDED. EYE BATH, WASHING FACILITIES, SAFETY SHOWER. Work Hygienic Practices:NOT PROVIDED Supplemental Safety and Health ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE. N/K = UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT DETERMINED. N/E = NOT ESTABLISHED. CNS = CENTRAL NERVOUS SYSTEM. GI = GASTROI NTESTINAL. SCBA = SELF CONTAINED BREATHING APPARATUS. ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:NEGLIGIBLE Spec Gravity:NOT PROVIDED Solubility in Water:APPRECIABLE Appearance and Odor:OFF-WHITE SOLID, ODORLESS. Percent Volatiles by Volume:NEGLIGIBLE Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS. Stability Condition to Avoid:NOT PROVIDED Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, SULFUR DIOXIDE =================== Toxicological Information =================== Toxicological Information:4-(METHYLAMINO)PHENOL SULFATE. BASED ON ANIMAL DATA, MAY CAUSE ADVERSE EFFECTS ON THE FOLLOWING ORGANS/SYSTEMS: BLOOD, KIDNEY, SPLEEN. BASED ON ANIMAL DATA THIS MATERIAL CAN PRODUCE METHEMOGLOBIN WHIC H, IN SUFFICIENT CONCENTRATION, CAUSES CYANOSIS, A BLUE-GRAY DISCOLORATION OF THE SKIN AND LIPS CAUSED BY A REDUCED ABILITY OF THE BLOOD TO CARRY OXYGEN. IN F-344 RATS, CHRONIC ORAL ADMINISTRATION OF HYDROQUINONE HAS RESULTED IN THE FORMATION OF BENIGN KIDNEY TUMORS THOUGHT TO BE SECONDARY TO NEPHROPATHY. CONTAINS: SODIUM TETRABORATE, PENTAHYDRATE. MAY CAUSE ADVERSE REPRODUCTIVE AND DEVELOPMENTAL EFFECTS. ===================== Ecological Information ===================== Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: 1-10. DAPHNID EC50 MG/L: 1-10. ALGAL IC50 MG/L: 10-100. ORGANICS READILY DEGR ADABLE (>70%): YES (7 DAYS). POTENTIAL BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 260. BOD5 (APPROXIMATE G/L): 205. POTENTIAL TOXICITY: WASTE TREATMENT MICROORGANISMS EC50 (MG/L): NOT A VAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNT OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EV EN AFTER CONTAINER IS EMPTIED. =================== MSDS Transport Information =================== Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE: (716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME), MONDAY THROUGH FR IDAY. ===================== Regulatory Information ===================== SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: HYDROQUINONE Federal Regulatory Information:NOT PROVIDED State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.