STATE CHEMICAL MANUFACTURING CO. -- FORMULA 190 -- 6840-00N010002
===================== Product Identification ===================== Product ID:FORMULA 190 MSDS Date:01/01/1988 FSC:6840 NIIN:00N010002 === Responsible Party === Company Name:STATE CHEMICAL MANUFACTURING CO. Address:3100 HAMILTON AVENUE City:CLEVELAND State:OH ZIP:44114 Info Phone Num:216-861-7114 Emergency Phone Num:216-861-7114 CAGE:53798 === Contractor Identification === Company Name:STATE CHEMICAL MANUFACTURING CO. Address:3100 HAMILTON AVENUE Box:City:CLEVELAND State:OH ZIP:44114-3701 Country:US Phone:216-861-7114 CAGE:53798 ============= Composition/Information on Ingredients ============= Ingred Name:PETROLEUM DISTILLATE Fraction by Wt: 95.83% Other REC Limits:500 PPM OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BROMACIL CAS:314-40-9 RTECS #:YQ9100000 Fraction by Wt: 0.98% Other REC Limits:N/K OSHA PEL:1 PPM ACGIH TLV:10 MG/M3; 9192 Ingred Name:2,4-D ESTERS (SARA III) CAS:25168-26-7 RTECS #:AG8575000 Fraction by Wt: 1.09% Other REC Limits:N/K EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:CHRONIC OVEREXPOSURE:CENTRAL NERVOUS SYSTEM DEPRESSION AND INTERNAL ORGAN DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES:IRRITANT.SKIN:IRRITANT.POSSIBLE CAUSE OF DERMATITIS.INHALATION:VAPORS ARE IRRITATING TO THE NOSE AND THROAT.INGESTION:HARMFUL OR FATAL IF SWALLOWED.OVEREXPOSURE MAY CAUSE NAUSEA,VOMITING.ASPIRATI ON INTO LUNGS CAUSES CHEMICAL PNEUMONIA. Medical Cond Aggravated by Exposure:BRONCHIAL CONDITIONS.SKIN IRRITATION AND DERMATITIS.EYE IRRITATION. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH EYES IMMEDIATELY WITH WATER FOR AT LEAST 15 MIN.GET MED ATTN.SKIN:WASH WELL WITH SOAP AND WATER.REMOVE CONTAMINATED SHOES AND CLOTHING.INHALATION:REMOVE TO FRESH AIR.USE ARTIFICIAL RESPIRAT ION IF NEEDED.GET MED ATTN.INGESTION:DONOT INDUCE VOMITING.ASPIRATION HAZARD DUE TO PETROLEUM DISTILLATES PRESENT.CONTACT MD IMMED. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:150F,65.56C Lower Limits:7.0% Upper Limits:1.0% Extinguishing Media:DRY CHEMICAL,CARBON DIOXIDE,FOAM AND WATER FOG. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT .A STRAIGHT STREAM OF WATER MAY SPREAD THE FIRE,HOWEVER,WATER SPREAD FROM AS FAR A (SEE SUPP) Unusual Fire/Explosion Hazard:VAPS ARE HEAVIER THAN AIR & MAY TRAVEL TO A DISTANT IGNITION SOURCE AND FLASHBACK.CNTRS INVOLVED IN FIRE MAY RUPTURE OR EXPLODE.AVOID ACCUMULATION (SEE SUPP) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF HEAT,SPARKS,OR FLAME.VENTILATE AREA.DIKE AREA TO CONTAIN SPILL.USE ABSORBANT OR VACUUMING TO COLLECT SPILL.DISPOSE OF PROPERLY.REPORTABLE QUANTITY OF 2,4-DICHLOROPHENOXYACETIC ACID,I SOOCTYL ESTER IS 100 LBS.TOXIC TO FISH & WILDLIFE. Neutralizing Agent:N/K ====================== Handling and Storage ====================== Handling and Storage Precautions:READ COMPLETE LABEL PRECAUTIONS BEFORE USING.DO NOT STORE NEAR POSSIBLE IGNIT SOURCES.STORE AWAY FROM FOOD,FEED,OR FERTILIZERS.STORE ONLY (SEE SUPP) Other Precautions:DO NOT EAT,SMOKE OR DRINK WHILE WORKING WITH THIS PRODUCT.WASH HANDS & OTHER EXPOSED AREAS W/ SOAP/WATER BEFORE EATING,DRINKING,OR SMOKING TO AVOID ACCIDENTAL INGESTION.WASH CONTAM CLTHG SEPARATE FROM OTHER LAUNDRY.FOR INDUSTRIAL (SEE SUP) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR CONCENTRATION BELOW TLV . Protective Gloves:RUBBER. Eye Protection:CHEMICAL WORKERS GOGGLES . Other Protective Equipment:RUBBER BOOTS IF NEEDED TO AVOID GETTING SKIN WET. Work Hygienic Practices:WASH W/ SOAP & WATER AFTER ALL CONTACT WITH THIS PRODUCT. Supplemental Safety and Health FIRE FIGHT PROC:DISTANCE AS POSSIBLE MAY BE USED TO COOL CNTRS INVOLVED IN FIRE.EXPLO HAZ:OF VAPORS.HAZ DECOMP PRODS MAY INCLUDE CO,CO*2,HCL & NITROGEN CONTAINING GASES.HNDLG/STOR PREC:IN ORIGINAL CNT R.STORE ABOVE 40F,4.4C.OTHER PRECS:AND INSTITUTIONAL USE ONLY.KEEP OUT OF REACH OF CHILDREN.VOLATILE BY WT >95%. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:350-500F Melt/Freeze Pt:M.P/F.P Text:N/K Decomp Temp:Decomp Text:N/K Vapor Pres:N/K Vapor Density:N/K Spec Gravity:0.85-0.9,H*2O=1 Evaporation Rate & Reference:N/K Solubility in Water:NEGLIGIBLE Appearance and Odor:TAN TO BROWN LIQUID WITH A PETROLEUM ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS,STRONG ACIDS OR BASES,SELECTED AMINES. Stability Condition to Avoid:IGNITION SOURCES,ELECTRICAL AREAS,HEAT,SPARKS AND OPEN FLAME. Hazardous Decomposition Products:CARBON MONOXIDE,CARBON DIOXIDE,HYDROGEN CHLORIDE,AND NITROGEN CONTAINING COMPOUNDS. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS .2,4-DICHLOROPHENOXYACETIC ACID,ISOOCTYL ESTER IS AN ACUTE HAZ WASTE UNDER RCRA.FOLLOW LABEL INSTRUCTIONS FOR DISPOSAL.DO NOT REUSE CNTR FOR ANY REASON. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.