E.I.DUPONT DE NEMOURS & CO. -- FREON 500 REFRIGERANT (DU001075) -- 6830-00-089-0697
===================== Product Identification ===================== Product ID:FREON 500 REFRIGERANT (DU001075) MSDS Date:06/10/1991 FSC:6830 NIIN:00-089-0697 === Responsible Party === Company Name:E.I.DUPONT DE NEMOURS & CO. Address:CHESTNUT RUN Box:80709 City:WILMINGTON State:DE ZIP:19898 Info Phone Num:302-774-2421 Emergency Phone Num:302-774-2421 Preparer's Name:W. J. BROCK CAGE:DO229 === Contractor Identification === Company Name:DU PONT E I DE NEMOURS AND CO INC PETROCHEMICALS DEPT Address:1251 BRANDYWINE BLDG Box:City:WILMINGTON State:DE ZIP:19898 Phone:302-773-5676 CAGE:73925 Company Name:E.I.DUPONT DE NEMOURS & CO INC Address:549 ALBANY STREET Box:1635 City:BOSTON State:MA ZIP:02118 Phone:800-441-7515 CAGE:DO229 ============= Composition/Information on Ingredients ============= Ingred Name:DICHLORODIFLUOROMETHANE (SARA III) (AUTOIGNIT = <1400F) CAS:75-71-8 RTECS #:PA8200000 Fraction by Wt: 73.8% OSHA PEL:1000 PPM 8 HR TWA ACGIH TLV:1000 PPM 8 HR TWA EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ozone Depleting Chemical:1 Ingred Name:DIFLUOROETHANE (AUTOIGNIT = <836F) CAS:75-37-6 RTECS #:KI1410000 Fraction by Wt: 26.2% Other REC Limits:1000PPM 8HR TWA, MFG OSHA PEL:NOT EST. ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE SUPLIMENTAL DATA. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:UNKNOWN IARC:UNKNOWN OSHA:YES Health Hazards Acute and Chronic:SKIN: POS FROST BITE/MILD IRRIT/SENSITIZATION. EYES: IRRIT/TEARING/BLURRY VISION. INHAL: POS NAUSEA/HEADACHE/WEAKNESS. TEMPORARY NS DEPRESSION W/DIZZINESS, HEADACHE, CONFUSION, INCOORDINATION, LOSS CO NSCIOUSNESS. HIGH EXPOS, >20% MAY LEAD TEMPORARY LUNG IRRIT W/COUGH/DISCOMFORT/DIFFICULT BREATHING/SHORTNESS BREATH;* Explanation of Carcinogenicity:CONTAINS 2-A [53-96-3] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. Effects of Overexposure:NK *TEMP ALTERATION OF HEART ELECTRICAL ACTIVITY W/IRREG PULSE/PALPITATIONS/INADEQUATE CIRCULATION/ABNORMAL KIDNEY FUNCTION/FATALITY FROM GROSS OVEREXPOSURE. Medical Cond Aggravated by Exposure:INDIVIDUALS W/PREEXISTING DISEASES OF CNS, CARDIOVASCULAR SYSTEM, LUNGS OR KIDNEYS MAY HAVE INCREASED SUSCEPTIBILITY TO TOXICITY OF EXCESSIVE EXPOSURES. ======================= First Aid Measures ======================= First Aid:INHAL: GET FRESH AIR IMMED. KEEP CALM. IF NOT BREATHING GIVE ARTIF RESP. IF BREATHING DIFFICULT, GIVE OXYGEN. CALL DR. SKIN: FLUSH W/WATER 15 MIN. IF FROST BITE, WARM AFFECTED AREAS. GET MED AID IF IR RIT PRESENT. EYES: FLUSH IMMED W/LOTS H2O 15 MIN. CALL DR. NOTE TO DR.: BECAUSE POS CARDIAC RHYTHM DISTURBANCE, CATECHOLANINE DRUGS (EPINEPHRINE) SHOULD BE USED W/SPECIAL CAUTION IN EMER LIFE SUPPORT. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:AS APPROPRIATE FOR COMBUSTIBLES IN AREA. Fire Fighting Procedures:SCBA REQUIRED IF CYLINDERS RUPTURE/RELEASE UNDER FIRE CONDITIONS. Unusual Fire/Explosion Hazard:USE WATER SPRAY/FOG TO COOL CONTAINERS. CYLINDERS ARE EQUIPPED W/TEMP & PRESSURE RELIEF DEVICES BUT MAY STILL RUPTURE UNDER FIRE CONDITIONS. DECOMP POSSIBLE. ================== Accidental Release Measures ================== Spill Release Procedures:REVIEW FIRE EXPLN HAZ/SAFETY PRECAUTIONS BEFORE CLEAN UP. USE APPROPRIATE PERSONAL PROTECTIVE EQUIP. VENTILATE AREA, ESPEC LOW PLACES WHERE VAPORS MIGHT COLLECT. USE SCBA FOR LARGE SPILLS. REMOVE OPEN FLAMES. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE CONTAINERS IN COOL, CLEAN DRY AREA. DO NOT ALLOW TEMP TO RISE ABOVE 125F. Other Precautions:AVOID BREATHING VAPORS. AVOID LIQUID CONTACT W/SKIN/EYES. USE SUFFICIENT VENTILATION TO KEEP EMPLOYEE EXPOSURE BELOW RECOMMENDED LIMITS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED UNDER NORMAL MFG CONDITIONS. SCBA REQUIRED IF SPILL OCCURS. Ventilation:NORMAL FOR STANDARD MFG ADEQUATE. LOCAL EXHAUST WHEN LG AMTS RELEASED. MECHANCL VENT SHOULD BE USED IN LOW PLACES. Protective Gloves:RUBBER,PLASTIC Eye Protection:CHEMICAL SPLASH GOGGLES Other Protective Equipment:USE GLOVES & FACE SHIELD WHEN HANDLING LIQUID Supplemental Safety and Health INHALATION 4-HR ALC = 383,000 PPM RATS. ORAL ALD RATS = >1500 MG/KG. ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:-28F (-33C) Vapor Pres:232 PSIA Vapor Density:3.7 Evaporation Rate & Reference:<1 (CCL4 - 1.0) Appearance and Odor:COLORLESS LIQUID, SLIGHT ETHERAL ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI/ALKALINE EARTHMETALS. AVOID POWDERED AL, ZN, BE,ETC. Stability Condition to Avoid:OPEN FLAMES, HIGH TEMPERATURES. Hazardous Decomposition Products:HYDROCHLORIC/HYDROFLUORIC ACIDS. POSSIBLY CARBONYL HALIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN COMPLIANCE W/APPLICABLE LAWS. RECLAIM BY DISTILLATION OR REMOVE TO PERMITTED WASTE DISPOSAL FACILITY. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.