ASHLAND CHEMICAL CO. DIV. OF ASHLAND OIL CO. INC. -- NAPHTHALENE #418505 -- 6810-00-286-6018
===================== Product Identification ===================== Product ID:NAPHTHALENE #418505 MSDS Date:12/22/1988 FSC:6810 NIIN:00-286-6018 === Responsible Party === Company Name:ASHLAND CHEMICAL CO. DIV. OF ASHLAND OIL CO. INC. Box:2219 City:COLUMBUS State:OH ZIP:43216 Country:US Info Phone Num:614-889-3333 Emergency Phone Num:606-324-1133 CAGE:5A188 === Contractor Identification === Company Name:ASHLAND CHEMICAL CO Address:5200 PAUL BLAZEL MEMORIAL PARKWAY Box:City:DUBLIN State:OH ZIP:43017 Country:US Phone:614-889-4505 CAGE:5A188 ============= Composition/Information on Ingredients ============= Ingred Name:NAPHTHALENE (SARA III) CAS:91-20-3 RTECS #:QJ0525000 Fraction by Wt: 100% OSHA PEL:10 PPM/15 STEL ACGIH TLV:10 PPM/15 STEL; 9192 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES- CAN CAUSE IRRITATION. SKIN- CAN CAUSE REDDENING, IRRITATION, DERMATITIS, POSSIBLE SENSITIZATION. INHALATION- MAY CAUSE HEADACHE, CONFUSION, NAUSEA AND VOMITING DEPENDING ON INDIVIDUAL SUSCEPTIBI LITY. INGESTION- CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA. Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. Effects of Overexposure:SEE HEALTH HAZARDS. OVEREXPOSURE TO THIS MATERIAL HAS BEEN SUGGESTED AS A CAUSE OF THE FOLLOWING EFFECTS IN HUMANS: KIDNEY DAMAGE, SPLEEN DAMAGE, AND EYE DAMAGE. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION: INDUCE VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:174F,79C Lower Limits:0.9 Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER FOG. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:VAPORS HEAVIER THAN AIR AND MAY TRAVEL ALONG THE GROUND OR BE MOVED BY VENTILATION AND IGNITED BY HEAT, PILOT LIGHTS, OTHER FLAMES AND IGNITION SOURCES. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILL: SWEEP UP ;M;ATERIAL FOR DISPOSAL OR RECOVERY. LARGE SPILL: PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FORM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. SHOVEL MATERIA L INTO CONTAINERS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. Other Precautions:CHRONIC OVEREXPOSURE: REPEATED EXPOSURE TO NAPHTHALENE MAY CAUSE CATARACTS AND ALLERGIC SKIN RASHES AND MAY CAUSE DESTRUCTION OF RED BLOOD CELLS WITH ANEMIA, FEVER, JAUNDICE AND KIDNEY AND LIVER DAMAG E. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED ORGANIC VAPOR CARTRIDGE AND DUST/MIST PRE-FILTER RESPIRATORS AS PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/ WARNINGS AND NIOSH-RESPIRATOR SELECTION. Ventilation:MECHANICAL (GENERAL) ROOM VENTILATION IS NORMALLY ADEQUATE. LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA NOT VENTED. Protective Gloves:NEOPRENE, NITRILE, VPC OR NATURAL RUBBER Eye Protection:SAFETY GOGGLES WITH OPTIONAL FACE SHIELD Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO NOT BREATHE VAPORS OR MISTS. ================== Physical/Chemical Properties ================== HCC:V4 Boiling Pt:B.P. Text:424F,218C Vapor Pres:0.08 Vapor Density:4.4 Spec Gravity:1.150 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.