EASTMAN KODAK COMPANY -- 146 3314,KODAK POTASSIUM FERRICYANIDE -- 6750-00-200-4527
===================== Product Identification ===================== Product ID:146 3314,KODAK POTASSIUM FERRICYANIDE MSDS Date:05/03/2000 FSC:6750 NIIN:00-200-4527 Status Code:A === Responsible Party === Company Name:EASTMAN KODAK COMPANY Address:343 STATE STREET City:ROCHESTER State:NY ZIP:14650 Country:US Info Phone Num:716-722-5151 Emergency Phone Num:(716) 722-5151 Preparer's Name:NOT PROVIDED. CAGE:19139 === Contractor Identification === Company Name:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS Address:343 STATE ST Box:City:ROCHESTER State:NY ZIP:14650-1115 Country:US Phone:716-722-5151/(800) 242-2424 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM FERRICYANIDE CAS:13746-66-2 RTECS #:LJ8225000 = Wt:100. ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) 2263 MG/KG Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. IF CYANIDE GAS IS LIBERATED DUE TO CONTACT WITH A STRONG ACID, IT MAY CAUSE DIZZINESS, HEADACHE, RAPID RESPIRATIO N, RAPID PULSE, UNCONSIOUSNESS, CONVULSIONS AND DEATH. EYES: CAUSES IRRITATION. HOWEVER, IMMEDIATE FLUSHING OF THE EYES WITH WATER WILL MINIMIZE ANY IRRITATIVE EFFECT. SKIN: LOW HAZARD FOR RECOMMENDED HANDLING. INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD. Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION (COMPONENTS PRESENT AT 0.1% OR MORE): - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NONE - INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NON E - NATIONAL TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE Effects of Overexposure:INHALATION: IF CYANIDE GAS IS LIBERATED DUE TO CONTACT WITH A STRONG ACID, IT MAY CAUSE DIZZINESS, HEADACHE, RAPID RESPIRATION, RAPID PULSE, UNCONSIOUSNESS, CONVULSIONS AND DEATH. EYES: CAUSES IRRITAT ION. Medical Cond Aggravated by Exposure:NOT PROVIDED. ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTEN TION IF SYMPTOMS PERSIST. SKIN: WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UN CONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:POWDERED MATERIAL MAY FORM EXPLOSIVE DUST-AIR MIXTURES. FIRE OR HIGH TEMPERATURES MAY CAUSE DECOMPOSITION. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT UP AND PUT IN A SUITABLE CONTAINER. AVOID GENERATING DUST. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NOT PROVIDED. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES (SEE INCOMPATIBILITY SECTION). KEEP FROM CONTACT WITH OXIDIZING MATERIALS. KEEP AWAY FROM HEAT. POWDERED MATERIAL MAY FORM EXPLOSI VE DUST-AIR MIXTURES. MINIMIZE DUST GENERATION AND ACCUMULATION. KEEP AWAY FROM SOURCES OF IGNITION. Other Precautions:AVOID PROLONGED OR REPEATED BREATHING OF DUST. AVOID CONTACT WITH EYES AND PROLONGED OR REPEATED CONTACT WITH SKIN. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. A FULL-FACE POSITIVE-PRESSURE AIR-SUPPLIED RESPIRATOR MUST BE WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE RELEASED OR HAVE BEEN RELEASED. SEE STABILITY AND REACTIV ITY SECTION. IF RESPIRATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING APPROPRIATE FOR RISK OF EXPOSURE Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES). Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER Work Hygienic Practices:NOT PROVIDED Supplemental Safety and Health SUPPLEMENTARY LOCAL EXHAUST VENTILATION, CLOSED SYSTEMS, OR RESPIRATORY PROTECTION MAY BE NEEDED IN SPECIAL CIRCUMSTANCES SUCH AS POORLY VENTILATED SPACES, MECHANICAL GENERATION OF DUSTS, HEATING, DR YING, ETC. ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT. Boiling Pt:B.P. Text:NOT RELEVANT. Melt/Freeze Pt:M.P/F.P Text:DECOMPOSES Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:NEGLIGIBLE Spec Gravity:1.89 Solubility in Water:APPRECIABLE Appearance and Odor:RED SOLID - ODORLESS Percent Volatiles by Volume:NEGLIGIBLE Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS. CONTACT WITH ACID LIBERATES FLAMMABLE MATERIAL, TOXIC GAS. Stability Condition to Avoid:STABLE. NO EXOTHERM TO: 310C BY HPDSC Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, CYANIDES. =================== Toxicological Information =================== Toxicological Information:ACUTE TOXICITY DATA: ORAL LD-50 (RAT): 2263 MG/KG DERMAL LD-50: 1 G/KG EYE IRRITATION (UNWASHED EYES): MODERATE EYE IRRITATION (WASHED EYES): SLIGHT SKIN IRRITATION: SLIGHT ===================== Ecological Information ===================== Ecological:POTENTIAL TOXICITY: FISH LC50 MG/L: >100. DAPHNID EC50 MG/L: 1-10. ALGAL IC50 MG/L: NOT AVAILABLE. ORGANICS READILY DEGRADABLE (>70%): NOT APPLICABLE. POTENTIAL BIOACCUMULATION: LOG POW <1. C OD (APPROXIMATE G/L): 605. BOD5 (APPROXIMATE G/L): 20. POTENTIAL TOXICITY: WASTE TREATMENT MICROORGANISMS EC50 (MG/L): NOT AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. CONTRACT WITH A LICENSED CHEMICAL DISPOSAL AGENCY. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WAR NINGS EVEN AFTER CONTAINER IS EMPTIED. =================== MSDS Transport Information =================== Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE: (716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME), MONDAY THROUGH FRIDAY. ===================== Regulatory Information ===================== SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: NONE Federal Regulatory Information:NOT PROVIDED. State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.