EASTMAN KODAK COMPANY -- 177 9123,KODAK EKTAMATIC S-30 STABILIZER -- 6750-01-387-7858
===================== Product Identification ===================== Product ID:177 9123,KODAK EKTAMATIC S-30 STABILIZER MSDS Date:12/06/2000 FSC:6750 NIIN:01-387-7858 Status Code:A === Responsible Party === Company Name:EASTMAN KODAK COMPANY Address:343 STATE STREET City:ROCHESTER State:NY ZIP:14650 Country:US Info Phone Num:716-477-3194 MSDS :800- 242-2424 Emergency Phone Num:716-722-5151 Preparer's Name:NOT PROVIDED CAGE:19139 === Contractor Identification === Company Name:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS Address:343 STATE ST Box:City:ROCHESTER State:NY ZIP:14650-1115 Country:US Phone:716-722-5151/(800) 242-2424 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:65. Maxumum % Wt:70. Other REC Limits:NOT PROVIDED Code:F Code:F Ingred Name:AMMONIUM THIOCYANATE CAS:1762-95-4 RTECS #:XK7875000 Minumum % Wt:20. Maxumum % Wt:25. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:NOT PROVIDED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETIC ACID CAS:64-19-7 RTECS #:AF1225000 Minumum % Wt:5. Maxumum % Wt:10. Other REC Limits:NOT PROVIDED OSHA PEL:10 PPM ACGIH TLV:10 PPM ACGIH STEL:15 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SODIUM ACETATE CAS:127-09-3 RTECS #:AJ4300010 Minumum % Wt:1. Maxumum % Wt:5. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:NOT PROVIDED Ingred Name:SODIUM BISULFITE CAS:7631-90-5 RTECS #:VZ2000000 < Wt:1. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:5 MG/M3 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT PROVIDED Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. IF HYDROGEN CYANIDE GAS IS LIBERATED, MAY CAUSE DIZZINESS, HEADACHE, RAPID RESPIRATION, RAPID PULSE, UNCONSCIOUSNESS, CONVULSIONS, DE ATH. IF SULFUR DIOXIDE GAS IS PRESENT, CAUSES RESPIRATORY IRRITATION. EYES: CAUSES IRRITATION. SKIN: CAUSES IRRITATION. HARMFUL IF ABSORBED THROUGH SKIN. THIS MATERIAL HAS A LOW POTENTIAL TO CAUSE ALL ERGIC SKIN REACTIONS; HOWEVER, CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN REPORTED. INGESTION: HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT. Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION (COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NON E - NATIONAL TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE Effects of Overexposure:INHALATION: IF HYDROGEN CYANIDE GAS IS LIBERATED, MAY CAUSE DIZZINESS, HEADACHE, RAPID RESPIRATION, RAPID PULSE, UNCONSCIOUSNESS, CONVULSIONS, DEATH. IF SULFUR DIOXIDE GAS IS PRESENT, CAUSES RESPIRAT ORY IRRITATION. EYES: CAUSES IRRITATION. SKIN: CAUSES IRRITATION. INGESTION: MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT. Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING, WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF SYMPTOMS O CCUR. SKIN: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. WASH CONTAMINATED CLOTHING BEFORE RE USE. DESTROY OR THOROUGHLY CLEAN CONTAMINATED SHOES. INGESTION: INDUCE VOMITING AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN OR POISON CONT ROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNT OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL C ONTAMINATION. Neutralizing Agent:NOT PROVIDED ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP FROM CONTACT WITH OXIDIZING MATERIALS. Other Precautions:AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. IF ACCIDENTALLY MIXED WITH A STRONG OXIDIZER OR ACID, DO NOT BREATHE GAS. AVOID BREATHING MIST OR VAPOR. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFT ER HANDLING. WARNING! CONTACT WITH A STRONG OXIDIZER OR ACID MAY LIBERATE HYDROGEN CYANIDE GAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, APPROVED RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: FULL-FACE ORGANIC VAPOR CARTRIDGE. A FULL-FACE POS ITIVE-PRESSURE AIR-SUPPLIED RESPIRATOR MUST BE WORN IF HAZARDOUS DECOMPOSITION PRODUCTS LIKELY TO BE/HAVE BEEN RELEASED. SEE OSHA STANDARD 29 CFR 1910.134. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING APPROPRIATE FOR RISK OF EXPOSURE Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES). Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER Work Hygienic Practices:NOT PROVIDED Supplemental Safety and Health SUPPLEMENTARY LOCAL EXHAUST VENTILATION, CLOSED SYSTEMS, OR RESPIRATORY PROTECTION MAY BE NEEDED IN SPECIAL CIRCUMSTANCES SUCH AS POORLY VENTILATED SPACES, EVAPORATION FROM LARGE SURFACES, SPRAYING, HEATING, ETC. ================== Physical/Chemical Properties ================== HCC:C3 NRC/State Lic Num:NOT RELEVANT Boiling Pt:>100.C, 212.F Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:68F: 24 MBAR (18 MM HG) Vapor Density:0.6 Spec Gravity:1.09 pH:4.5 Viscosity:NOT PROVIDED Evaporation Rate & Reference:NOT PROVIDED Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID, SLIGHT ODOR Percent Volatiles by Volume:> 65 WT Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS (E.G. SODIUM HYPOCHLORITE (BLEACH)), BASES, STRONG ACIDS (E.G. SULFURIC ACID). CONTACT WITH STRONG OXIDIZING AGENTS OR ACIDS LIBERATES POISONOUS GAS, FLAMMABLE MATERIAL. Stability Condition to Avoid:CONTACT WITH BASE LIBERATES FLAMMABLE MATERIAL. Hazardous Decomposition Products:CYANIDES, CARBONYL SULFIDE, AMMONIA, CHLORAMINE, CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, OXIDES OF SULFUR. =================== Toxicological Information =================== Toxicological Information:EFFECTS OF EXPOSURE: GENERAL: CONTAINS: AMMONIUM THIOCYANATE. OVEREXPOSURE TO THIOCYANATES HAS BEEN SHOWN TO CAUSE THYROID ENLARGEMENT, DECREASE IN METABOLIC RATE, AND SYMPTOMS OF HYPOTHYROIDISM IN HUMANS AND ANIMALS. ===================== Ecological Information ===================== Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: >100. DAPHNID EC50 MG/L: >100. ALGAL IC50 MG/L: >100. ORGANICS READILY DEGRAD ABLE (>70%): YES (7 DAYS). POTENTIAL BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 97. BOD5 (APPROXIMATE G/L): 44. POTENTIAL TOXICITY: WASTE TREATMENT MICROORGANISMS EC50 (MG/L): >100. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNT OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EV EN AFTER CONTAINER IS EMPTIED. =================== MSDS Transport Information =================== Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE: (716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME), MONDAY THROUGH FRIDAY . ===================== Regulatory Information ===================== SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: AMMONIUM THIOCYANATE AS A SO URCE OF AQUEOUS AMMONIA. Federal Regulatory Information:NOT PROVIDED State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.