EASTMAN KODAK COMPANY -- 146 4627, CONCENTRATE, KODAK SELECTOL - SOFT DEVELOPER -- -
===================== Product Identification ===================== Product ID:146 4627, CONCENTRATE, KODAK SELECTOL - SOFT DEVELOPER MSDS Date:02/21/2001 FSC:NIIN:Submitter:D DG Status Code:A === Responsible Party === Company Name:EASTMAN KODAK COMPANY Address:343 STATE STREET City:ROCHESTER State:NY ZIP:14650 Country:US Info Phone Num:716-477-3194 MSDS :800- 242-2424 Emergency Phone Num:716-722-5151 Preparer's Name:NOT PROVIDED CAGE:19139 === Contractor Identification === Company Name:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS Address:343 STATE ST Box:City:ROCHESTER State:NY ZIP:14650-1115 Country:US Phone:716-722-5151/(800) 242-2424 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM CARBONATE CAS:497-19-8 RTECS #:VZ4050000 Minumum % Wt:40. Maxumum % Wt:45. Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Minumum % Wt:40. Maxumum % Wt:45. Ingred Name:SODIUM HEXAMETAPHOSPHATE CAS:10124-56-8 RTECS #:OY3675000 Minumum % Wt:5. Maxumum % Wt:10. EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:4-(METHYLAMINO)PHENOL SULFATE CAS:55-55-0 RTECS #:SL8650000 Minumum % Wt:5. Maxumum % Wt:10. Ingred Name:POTASSIUM BROMIDE CAS:7758-02-3 RTECS #:TS7650000 Minumum % Wt:1. Maxumum % Wt:5. ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT PROVIDED Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION: HARMFUL IF INHALED. AIRBORNE DUST IRRITATING. MAY CAUSE IRRITATION TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES LIBERATE SULFUR DIOX IDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO RESPIRATORY TRACT. EYES: CAUSES IRRITATION. AIRBORNE DUST IRRITATING. HOWEVER, IMMEDIATE FLUSHING OF EYES WITH WATER WILL MINIMIZE IRRITATIVE EFFECT. SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION BASED ON HUMAN EXPERIENCE. INGESTION: HARMFUL IF SWALLOWED. MAY CAUSE BURNS OF GASTROINTESTINAL TRACT IF SWALLOWED. Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION (COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NON E - NATIONAL TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE Effects of Overexposure:INHALATION: AIRBORNE DUST IRRITATING. MAY CAUSE IRRITATION TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOX IDE GAS IS IRRITATING TO RESPIRATORY TRACT. EYES: CAUSES IRRITATION. AIRBORNE DUST IRRITATING. SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION BASED ON HUMAN EXPERIENCE. INGESTION: MAY CAUSE BURNS OF GASTROINTESTINAL TRACT IF SWALLOWED. Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING, WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA. ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. SKIN : IMMEDIATELY FLUSH WITH WATER AT LEAST 15 MINUTES, REMOVING CONTAMINATED CLOTHING AND SHOES. IF SKIN IRRITATION OR ALLERGIC SKIN REACTION DEVELOPS, GET MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING B EFORE REUSE. INGESTION: IF SWALLOWED, INDUCE VOMITING AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. GIVE VICTIM GLASS OF WATER ===================== Fire Fighting Measures ===================== Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE (NONCOMBUSTIBLE) ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNT OF WATER. OTHERWISE, SWEEP UP AND PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES (SEE INCOMPATIBILITY SECTION). Other Precautions:AVOID BREATHING DUST. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW EXPOSURE LIMITS, APPROVED RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: N95 PARTICULATE FILTER. RESPIRATOR SHOULD BE WORN IF HAZARDOU S DECOMPOSITION PRODUCTS ARE LIKELY OR HAVE BEEN RELEASED. RESPIRATOR: ACID GAS. IF RESPIRATORS ARE USED, ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation:USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING APPROPRIATE FOR RISK OF EXPOSURE Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES). Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER Work Hygienic Practices:NOT PROVIDED Supplemental Safety and Health ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE. N/K = UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT DETERMINED. N/E = NOT ESTABLISHED. CNS = CENTRAL NERVOUS SYSTEM. GI = GASTROI NTESTINAL. SCBA = SELF CONTAINED BREATHING APPARATUS. ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:GET MEDICAL ATT Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:NEGLIGIBLE Spec Gravity:>1.0 Viscosity:NOT AVAILABLE Evaporation Rate & Reference:NEGLIGIBLE Solubility in Water:APPRECIABLE Appearance and Odor:WHITE, SOLID. ODOR: ODORLESS. Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS. Stability Condition to Avoid:NOT PROVIDED Hazardous Decomposition Products:SULFUR DIOXIDE, NITROGEN OXIDES (NOX), CARBON DIOXIDE, CARBON MONOXIDE =================== Toxicological Information =================== Toxicological Information:EFFECTS OF EXPOSURE: GENERAL: CONTAINS 4-(METHYLAMINO)PHENOL SULFATE. BASED ON ANIMAL DATA, MAY CAUSE ADVERSE EFFECTS ON THE FOLLOWING ORGANS/SYSTEMS: BLOOD, KIDNEY, SPLEEN. BASED ON ANIMAL DATA THIS MATERIAL CAN PRODUCE METHEMOGLOBIN WHICH, IN SUFFICIENT CONCENTRATION, CAUSES CYANOSIS, A BLUE-GRAY DISCOLORATION OF THE SKIN AND LIPS CAUSED BY A REDUCED ABILITY OF THE BLOOD TO CARRY OXYGEN. ===================== Ecological Information ===================== Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: 1-10. DAPHNID EC50 MG/L: 1-10. ALGAL IC50 MG/L: 10-100. ORGANICS READILY DEGR ADABLE (>70%): YES (14 DAYS). POTENTIAL BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 115. BOD5 (APPROXIMATE G/L): 89. POTENTIAL TOXICITY: WASTE TREATMENT MICROORGANISMS EC50 (MG/L): >100. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNT OF WATER. =================== MSDS Transport Information =================== Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE: (716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME), MONDAY THROUGH FR IDAY. ===================== Regulatory Information ===================== SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: NONE Federal Regulatory Information:NOT PROVIDED State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.