AMOCO OIL COMPANY -- AMOCO REGULAR LEAD-FREE GASOLINE -- 9130-01-208-4172
===================== Product Identification ===================== Product ID:AMOCO REGULAR LEAD-FREE GASOLINE MSDS Date:09/24/1993 FSC:9130 NIIN:01-208-4172 === Responsible Party === Company Name:AMOCO OIL COMPANY Address:200 EAST RANDOLPH DRIVE City:CHICAGO State:IL ZIP:60601 Country:US Info Phone Num:312-856-3907 Emergency Phone Num:800-447-8735 (HEALTH) Preparer's Name:DONALD M. BARKER, DIR CAGE:15958 === Contractor Identification === Company Name:AMOCO OIL CO Address:200 E RANDOLPH DR Box:City:CHICAGO State:IL ZIP:60601-6401 Country:US Phone:312-856-3907- EM HLTH: 800 447-8735 CAGE:15958 ============= Composition/Information on Ingredients ============= Ingred Name:GASOLINE CAS:8006-61-9 RTECS #:LX3300000 Fraction by Wt: N/GIVEN Other REC Limits:NONE RECOMMENDED OSHA PEL:300 PPM ACGIH TLV:300 PPM/500STEL;9394 Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: 4% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1028 ACGIH TLV:10 PPM; A2; 9394 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:ETHYL BENZENE (SARA III) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 2% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/125STEL;9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 22% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM; Z-2 ACGIH TLV:S, 50 PPM; 9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CYCLOHEXANE (SARA III) CAS:110-82-7 RTECS #:GU6300000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:300 PPM ACGIH TLV:300 PPM, 9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL;9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHYL TERT-BUTYL ETHER (SARA III) CAS:1634-04-4 RTECS #:KN5250000 Fraction by Wt: 15% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:BUTANE CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: N/GIVEN Other REC Limits:NONE RECOMMENDED OSHA PEL:800 PPM ACGIH TLV:800 PPM; 9394 Ingred Name:N-HEPTANE CAS:142-82-5 RTECS #:MI7700000 Fraction by Wt: N/GIVEN Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM ACGIH TLV:400 PPM/500STEL;9394 Ingred Name:HEXANE (N-HEXANE) CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: N/GIVEN Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM ACGIH TLV:50 PPM; 9394 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:PENTANE CAS:109-66-0 RTECS #:RZ9450000 Fraction by Wt: N/GIVEN Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:600 PPM/750STEL;9394 Ingred Name:TRIMETHYL BENZENE (SARA III) CAS:25551-13-7 RTECS #:DC3220000 Fraction by Wt: N/GIVEN Other REC Limits:NONE RECOMMENDED OSHA PEL:25 PPM ACGIH TLV:25 PPM; 9394 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RATS) = 18.8ML/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:EYE:HIGH CONCEN OF VAP/MIST MAY CAUSE DISCOMFORT. SKIN:PRLONG/REPEAT CONTACT CAN DEFAT & LEAD TO IRRIT &/OR DERM. INHAL:VAPOUR HARMFUL. HIGH VAP CONCEN CAN CAUSE HEADACHES, DIZZINESS, DROWSINESS, NAUS EA. INGEST:LOW VISCOSITY PRODUCT. HARMFUL/FATAL IF ASPIRATED INTO LUNGS CAUSING CHEM PNEUMONIA/FATAL. Explanation of Carcinogenicity:CONTAINS BENZENE WHICH IS KNOWN TO CAUSE CANCER. Effects of Overexposure:MAY PRODUCE HEADACHES, DIZZ, NAU, DROWSINESS, IRRIT OF EYE/NOSE/THROAT/CNS DEPRESSION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MFG. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/PLENTY OF WATER. GET MED ATTN IF IRRIT PERSISTS. SKIN:WASH W/SOAP & WATER. REMOVE CONTAMIN CLOTHING/SHOES. GET MED ATTN IF IRRIT DEVELOPS. INHAL:REMOVE TO UNCONTAMINATED AREA. GIVE ARTIFIC IAL RESP IF NOT BREATHING. GET MED ATTN. INGEST:DO NOT INDUCE VOMIT. GET IMMED MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point:-45F,-43C Autoignition Temp:Autoignition Temp Text:495F Lower Limits:1.3 Upper Limits:7.6 Extinguishing Media:AGENTS APPROVED FOR CLASS B HAZARDS (E.G. DRY CHEMICAL, CARBON DIOXIDE, HALOGENATED AGENTS, FOAM, STEAM) OR WATER FOG. Fire Fighting Procedures:NONE SPECIFIED BY MFG. HOWEVER WEAR SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE EQPMT IF SITUATION WARRENTS. Unusual Fire/Explosion Hazard:EXTREMELY FLAMM VAP/AIR MIXTURES FORM. EXTINGUISHMENT OF FIRE BEFORE SURCE OF VAP IS SHUT OFF CAN CREATE AN EXPLOSIVE MIXTURE IN AIR. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE/SHUT OFF ALL IGN SOURCES.USE WATER SPRAY TO DISPERSE VAP.INCREASE VENTILATION IF POSSIBLE.CONTAIN ON ABSORBENT MATL(SAND/SAWDUST/DIRT/CLAY).KEEP OUT OF SEWERS & WATERWAYS.REPORT SPILLS TO APPRO PRIATE AUTHORITIES. Neutralizing Agent:NONE SPECIFIED BY MFG. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN FLAMM LIQ STORAGE AREA. KEEP CNTNR CLOSED. STORE AWAY FROM HEAT/ING SOURCES/OPEN FLAME IAW APPLICABLE FED/STATE/LOC REGS. Other Precautions:KEEP AWAY FROM IGNITION SOURCES. KEEP CONTAINER CLOSED. USE W/ADEQUATE VENTILATION. ABOID BREATHING VAPOR &/OR MIST. USE AS MOTOR FUEL ONLY. AVOID STRONG OXIDIZERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION IS INADEQUATE USE NIOSH/MSHA CERTIFIED RESP WHICH WILL PROTECT AGAINST ORGANIC VAP/MIST. Ventilation:USE WITH ADEQUATE VENTILATION. Protective Gloves:RECOMMENDED-PVC. Eye Protection:RECOMMENDED-SAFETY GLASSES/GOGGLES. Other Protective Equipment:WEAR PROTECTIVE CLOTHING IF PRLONGED/REPEATED CONTACT IS LIKELY. Work Hygienic Practices:THOROUGHLY CLEAN/DRY CONTAMIN CLOTHING BEFORE REUSE. WASH HANDS AFTER HANDLING & BEFORE EAT/SMOKE/DRINK. Supplemental Safety and Health LONG-TERM INHAL STUDY OF WHOLE UNLEADED GASOLINE VAP EXPOSURE-RELATED KIDNEY DAMAGE/TUMORS WERE OBSERVED IN MALE RATS & NOT SEEN IN FEMALES.CHRONIC EXPOSURE TO BENZENE CAUSES LEUKEMIA IN HUMAND & OTHE R ADVERSE BLOOD EFFECTS (ANEMIA). ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:80.0F,26.7C Vapor Pres:7-15LBS Vapor Density:3-4 Spec Gravity:0.75 Solubility in Water:NEGLIGIBLE, <0.1% Appearance and Odor:CLEAR, BRIGHT LIQUID, CHARACTERISTIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CHLORINE, FLUORINE AND OTHER STRONG OXIDIZERS. Stability Condition to Avoid:BURNING CAN BE STARTED EASILY. KEEP AWAY FROM IGNITION SOURCES (D.G. HEAT/SPARKS/OPEN FLAMES). Hazardous Decomposition Products:BURNING CAN PRODUCE CARBON MONOXIDE &/OR CARBON DIOXIDE AND OTHER HARMFUL PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:RESIDUES/SPILLED MATL ARE HAZ WASTE DUE TO IGNITABILITY. DISPOSAL MUST BE IAW APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. ENCLOSED-CONTROLLED INCINERATION IS RECOMMENDED UNLESS DIRECTED OTHERWISE BY APPLICABLE ORDINANCES. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.