ASHLAND CHEMICAL CO, IC & S DIVISION -- ETHYLENE GLYCOL -- 6810-01-044-5726
===================== Product Identification ===================== Product ID:ETHYLENE GLYCOL MSDS Date:05/31/1989 FSC:6810 NIIN:01-044-5726 === Responsible Party === Company Name:ASHLAND CHEMICAL CO, IC & S DIVISION Box:2219 City:COLUMBUS State:OH ZIP:43216 Country:US Info Phone Num:614-889-3333 Emergency Phone Num:614-889-3333, 800-274-5263 CAGE:5A188 === Contractor Identification === Company Name:ASHLAND CHEMICAL CO Address:5200 PAUL BLAZEL MEMORIAL PARKWAY Box:City:DUBLIN State:OH ZIP:43017 Country:US Phone:614-889-4505 CAGE:5A188 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL (SARA III) CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 100% OSHA PEL:C 50 PPM ACGIH TLV:C 50 PPM,VAPOR; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 4700 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE- INHALATION:IRRITATION OF NASAL AND REPIRATORY SYSTEM. EYES/SKIN:IRRITATION. INGESTION:GASTROINTESTINAL IRRITATION. CHRONIC:CNS EFFECTS, LIVER AND KIDNEY DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYE/SKIN:IRRITATION. INHALATION:NASAL AND RESPIRATORY IRRITATION, COUGHING. INGESTION:NAUSEA, VOMITING & DIARRHEA. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS MAY BE AGGRAVATED BY OVEREXPOSURE. ======================= First Aid Measures ======================= First Aid:SKIN: WASH AREA WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES.SEE DOCTOR. SWALLOWED: GIVE 2 GLASSES OF WATER. IF CONSCIOUS, INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR.GIVE OXYGEN IF NEEDED, IF BREATHING STOPS, RESUSCITATE. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=111.C, 231.8F Lower Limits:3.2 % Upper Limits:15.3 % Extinguishing Media:WATER FOG, CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FULL PROTECTIVE GEAR AND SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:WATER OR FOAM MAY CAUSE FROTHING OF BURNING MATERIAL. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. RECOVER LIQUID BY VACUUMING, OR ABSORB LIQUID ON VERMICULITE OR OTHER INERT ABSORBENT MATERIAL AND TRANSFER TO CONTAINER FOR DISPOSAL. Neutralizing Agent:NONE ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A CLEAN, DRY AREA. VENTILATE WELL. STORE AWAY FROM IGNITION SOURCES. Other Precautions:KEEP AWAY FROM CHILDREN ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. USE NIOSH APPROVED RESPIRATOR IF TLV/PEL EXCEEDED. Ventilation:USE ADEQUATE MECHANICAL VENTILATION. Protective Gloves:NITRILE RUBBER Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES Other Protective Equipment:WEAR IMPERVIOUS CLOTHING TO PREVENT PROLONGED OR REPEATED CONTACT. Work Hygienic Practices:PRACTICE GOOD PERSONAL HYGENE AFTER USE. DO NOT EAT, DRINK, SMOKE UNTIL HANDS ARE WASHED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V5 Boiling Pt:=193.C, 379.4F Vapor Pres:<.1 Vapor Density:2.2 Spec Gravity:1.115 Evaporation Rate & Reference:<1.0 (N-BUTYL ACETATE=1) Solubility in Water:APPRECIABLE Appearance and Odor:CLEAR, SYRUPY LIQUID. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS AND STRONG ALKALIS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT LOCAL ENVIRONMENTAL MANAGER. INCINERATE OR DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.