BRULIN & CO INC -- SOLVENT DEGREASER -- 6850-00N060967
===================== Product Identification ===================== Product ID:SOLVENT DEGREASER MSDS Date:02/16/1993 FSC:6850 NIIN:00N060967 === Responsible Party === Company Name:BRULIN & CO INC Box:270 City:INDIANAPOLIS State:IN ZIP:46206-0270 Country:US Info Phone Num:317-923-3211 Emergency Phone Num:800-424-9300(CHEMTREC) CAGE:IO291 === Contractor Identification === Company Name:BRULIN & CO INC Box:UNKNOW CAGE:94054 Company Name:BRULIN & CO INC Box:270-B City:INDIANAPOLIS State:IN ZIP:46206-0270 Country:US Phone:317-923-3211;800-428-7149 CAGE:IO291 ============= Composition/Information on Ingredients ============= Ingred Name:METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313) (CERCLA). VP:340 @ 68F. CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: 19% OSHA PEL:500 PPM ACGIH TLV:50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYLENE, TETRACHLORO-; (PERCHLOROETHYLENE) (SARA 313) (CERCLA) CAS:127-18-4 RTECS #:KX3850000 Fraction by Wt: 30% OSHA PEL:100 PPM ACGIH TLV:25 PPM;100 STEL EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:PROPYLENE OXIDE (SARA 302/313) (CERCLA) CAS:75-56-9 RTECS #:TZ2975000 Fraction by Wt: 0.09% OSHA PEL:100 PPM ACGIH TLV:20 PPM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:STODDARD SOLVENT; (ALIPHATIC PETROLEUM DISTILLATES) CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 50-70% OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:SUPDAT:ANNUAL REPORT ON CARCINOGENS, 1994:ANTICIPATED TO BE CARCINOGEN. ANIMAL:BLOOD, GI. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:PRLNG/RPTD SKIN CONT MAY CAUSE DERM. INGS 1 & 2 HAVE BEEN SHOWN TO INCR RATE OF SPONT OCCURRING (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:MALIGNANT TUMORS IN CERTAIN MICE & LAB RATS. CHLOROCARBON MATLS HAVE PRDCD SENSIT OF MYOCARDIUM TO (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY EXPOS TO CHLOROCARBONS . RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:LUNGS IF ASPIR & CAUSE SYSTEMIC EFTS, DECISION WHETHER TO INDUCE VOMIT/NOT SHOULD BE MADE BY MD. (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:INGS 1 & 2 MAY INCR "MYOCARDIAL IRRITABILITY". DO NOT ADMIN SYMPATHO-MIMETIC DRUGS UNLESS ABSOLUTELY NEC.(ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:EXCESSIVE EXPOS MAY CAUSE CARBOXYHEMOGLOBINEMIA THEREBY IMPAIRING BLOODS ABILITY TO TRANSPORT OXYGEN. RTECS #:9999999ZZ Ingred Name:PROT GLOVES:POLYFLUORINATED POLYETHYLENE OR VITON. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:EXCESSIVE INHAL/INGEST MAY PRDCE SYMPS OF CNS DEPRESS. EXPOS TO EYES/SKIN MAY CAUSE IRRIT. LOW TO MOD TOX BY INGEST; HOWEVER, IF ASPIR MAY CAUSE CHEM PNEUM. SKIN CONT MAY PRDCE REDNESS & PAIN. R PTD CONT MAY CAUSE DRYING OF SKIN. EYE CONT MAY PRDCE PAIN, REDNESS & TEARING. OVEREXP BY INHAL MAY (EFTS OF OVEREXP) Explanation of Carcinogenicity:METHYLENE CHLORIDE:IARC MONOGRAPHS SUPP, VOL 7, PG 194, 1987:GRP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC (SUPDAT) Effects of Overexposure:HLTH HAZ:RSLT IN HDCHS, DIZZ, NAUS, DROW. PRLNG OVEREXP MAY CAUSE UNCON/EVEN DEATH. INGEST MAY CAUSE ABDOM PAIN, NAUS, VOMIT, DIARR. ABSORPTION THRU GI TRACT MAY PRDCE SIMILAR SYMPS TO EXCESSIVE INHAL . ALCOHOL CONSUMED BEFORE/AFTER EXPOS MAY INCR ADVERSE EFTS. CHRONIC:PRLNG/RPTD INHAL MAY DMG LIVER & KIDNEYS. (ING 6) Medical Cond Aggravated by Exposure:THOSE W/HISTORY OF HEART DISEASE, ANGINA OR WHO ARE HEAVY DRINKERS OR SMOKERS SHOULD AVOID EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/LG AMTS OF WATER FOR AT LST 15 MINS LIFTING UPPER & LOWER LIDS OCCAS. GET MED ATTN. INHAL:REMOVE TO FRESH AIR. ADMIN OXYGEN IF BRTHG IS DFCLT. GET MED ATTN. SKIN:WASH W/MILD SOAP & WATER. REMOVE CONTAM CLTHG & LAUNDER BEFORE REUSE. INGEST:DO NOT INDUCE VOMIT. CALL MD/LOC POIS CTL CTR IMMED/TRANSPORT TO EMER FACILITY IMMED. NOTE TO MD:BECAUSE RAPID ABSORPTION MAY OCCUR THRU (ING 10) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:185F,85C Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA & FULL PROTECTIVE EQUIPMENT . WATER FOG MAY BE USED TO COOL CLOSED CONTAINERS. Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL & PHOSGENE . NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY). ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AREA WELL. ABSORB ON SOLID ABSORBENT & SHOVEL INTO CONTAINERS. FOR LARGE SPILLS, RECOVER W/VACUUM TRUCK. CONT APPRVD WASTE SOLV DISP COMPANY. RQ:ING 1:1000 LB S. ING 2:1 LB. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE CONTAINERS IN A COOL, DRY, WELL VENTILATED AREA. AVOID BREATHING OF VAPORS OR MIST. FUMES ARE HVR/AIR & WILL SETTLE IN CONFINED LOW AREAS. Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV RADIATION MAY CAUSE THE FORMATION OF HCL &/OR PHOSGENE . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV(S) IS EXCEEDED, USE A NIOSH/MSHA APPROVED RESPIRATOR. NIOSH/MSHA APPROVED SELF CONTAINED BREATHING APPARATUS FOR EMERGENCY USE. Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Protective Gloves:RESISTANT GLOVES SUCH AS (ING 13) Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS . Other Protective Equipment:AS NECESSARY TO PREVENT SKIN CONTACT. IF SPLASHING IS PROBABLE, AN EYE WASH & SAFETY SHOWER SHOULD BE AVAILABLE. Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE USED. Supplemental Safety and Health EXPLAN OF CARCIN:TO BE CARCIN. ANIMAL:LUNG, LIVER, SALIVARY, MAMMARY GLAND (TUMORS). TETRACHLOROETHYLENE:IARC MONOGRAPHS, SUPP, VOL 7, PG 355, 1987:GRP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO BE CARCIN. ANIMAL:LIVER TUMORS. PROPYLENE OXIDE:IARC MONOGRAPHS, SUPP, VOL 7, PG 328, 1987:GRP 2B. NTP 7TH (ING 5) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>104F,>40C Vapor Pres:SEE ING 1 Vapor Density:>3 Spec Gravity:1.01 (H*2O=1) Evaporation Rate & Reference:2.5 (N-BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:COLORLESS LIQUID; NAPHTHA/CHLORINATED ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI METALS, OPEN FLAMES, ELECTRICAL ARCS. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN CHLORIDE, TRACES OF PHOSGENE UPON THERMAL DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE ACCORDING TO FEDERAL, STATE & LOCAL LAWS & 40 CFR. 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