GILLETTE MEDICAL EVALUATION LABS -- LIQUID PAPER CORRECTION FLUID -- 7510-01-396-1184
===================== Product Identification ===================== Product ID:LIQUID PAPER CORRECTION FLUID MSDS Date:11/28/1989 FSC:7510 NIIN:01-396-1184 === Responsible Party === Company Name:GILLETTE MEDICAL EVALUATION LABS Address:401 PROFESSIONAL DR City:GAITHERSBURG State:MD ZIP:20879 Country:US Info Phone Num:301-590-9781 Emergency Phone Num:301-590-9781 CAGE:9A977 === Contractor Identification === Company Name:GILLETTE MEDICAL EVALUATION Box:UNKNOW CAGE:GXLLE Company Name:GILLETTE MEDICAL EVALUATION LABORATORIES Address:1413 RESEARCH BOULEVARD City:ROCKVILLE State:MD ZIP:20850 Phone:301-424-2000 CAGE:9A977 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANE, 1,1,1-TRICHLORO-; (1,1,1-TRICHLOROETHANE) (SARA 313) (CERCLA) CAS:71-55-6 RTECS #:KJ2975000 OSHA PEL:350 PPM ACGIH TLV:350 PPM/450STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ozone Depleting Chemical:1 Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:RESIN OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:NAPHTHA, HEAVY ALKYLATE; (MINERAL SPIRITS) CAS:64741-65-7 OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:PHTHALIC ACID, BIS(2-ETHYLHEXYL) ESTER; (DI(2-ETHYLHEXYL)PHTHALATE) CAS:117-81-7 RTECS #:TI0350000 OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:ISOTHIOCYANIC ACID, ALLYL ESTER; (MUSTARD OIL) CAS:57-06-7 RTECS #:NX8225000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:COLORANT AND VARIOUS DYES OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUP DAT: EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS . RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: DO NOT USE SYMPATHOMIMETIC AGENTS (E.G., EPINEPHRINE) IN HALOGENATED HYDROCARBON POISONING (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: BECAUSE OF POSSIBLE INDUCTION OF VENTRICULAR FIBRILLATION. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): > 5 ML/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: NONE ANTIC UNDER FORESEEABLE USE CNDTNS. IF VAPS ARE DELIBERATELY CONC & INHALED (ABUSE), FOLLOWING SYMP MAY OCCUR: RESP IRRIT, DIZZ, DROW, HDCH, NAUS, UNCON, CARD SENSIT (ABNORM HEARTBE AT), COMA & DEATH. (MUSTARD OIL IS ADDED TO PROD AS ABUSE DETERRENT.) INGEST: NONE ANTIC UNDER (EFFECTS OF OVEREXPOSURE) Explanation of Carcinogenicity:PHTHALIC ACID, BIS(2-ETHYLHEXYL)ESTER: IARC MONO, SUPP, VOL 7, PG 56, 1987: GROUP 2B. NTP 7TH ANNUAL REPORT ON (SUP DAT) Effects of Overexposure:HLTH HAZ: FORESEEABLE USE CNDTNS. DEPENDING ON AMT INGESTED, MOST OF SYMP DESCRIBED ABOVE MAY OCCUR. SKIN: NONE ANTIC UNDER FORESEEABLE USE CNDTNS. IRRIT MAY OCCUR IF CONT IS PRLNG/RPTD. SKIN ABSORPTI ON: NONE ANTIC UNDER FORESEEABLE USE CNDTNS. SOLV CAN BE ABSORBED THRU SKIN (PRLNG CONT), BUT NOT LIKELY IN (SUP DAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN. IF IRRIT PERSISTS, OBTAIN MED ATTN. SKIN: WASH W/SOAP & WATER. INHAL: NONE NORMALLY ANTIC. IN ABUSE SITUATION, IF BRTHG HAS STOPPED, ADMIN ARTF RESP & SEEK MED ATTN IMMED. INGEST: CONSULT MD. NOTES TO MD: THE FORMULATION CONTAINS LESS THAN 5% PETRO DISTIL. INDUCTION OF VOMIT SHOULD BE CONSIDERED AT THE DISCRETION OF MD. (ING 9) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>200F,>93C Extinguishing Media:AS FOR ADJACENT FIRE: DRY CHEMICAL, FOAM, CARBON DIOXIDE, WATER FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:CONCENTRATED VAPOR OF 1,1,1-TRICHLOROETHANE CAN BURN, PRODUCING HAZARDOUS DECOMP PRODUCTS. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL AND PHOSGENE . ================== Accidental Release Measures ================== Spill Release Procedures:PICK UP SPILLS WITH TOWELS, TISSUES, ETC, AND PLACE IN TRASH. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:NO UNUSUAL HANDLING OR STORAGE WHEN USED AS DIRECTED. WHEN STORED IN LARGE QUANTITIES (AS IN WAREHOUSE), IT SHOULD BE IN WELL-VENTILATED, COOL AREA. Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE UNDER NORMAL USE CONDITIONS. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE UNDER NORMAL USE CNDTNS. PRODUCT IS NON-HAZARDOUS WHEN USED AS DIRECTED IN AN OFFICE/ROOM W/NORMAL AIR CIRCULATION. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS . Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health CARCIN EXPLAN: CARCINS, 1994: ANTIC TO BE CARCIN. ANIMAL: LIVER, TESTES. EFTS OF OVEREXP: ACUTELY TOX AMTS. EYE: IRRIT. CHLOROCARBON MATLS HAVE PRODUCED SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIM ALS & COULD HAVE SIMILAR EFT IN HUMANS.ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED (ING 8) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:165F,74C Vapor Pres:100 Vapor Density:4.5 Spec Gravity:1.7 (H*2O=1) Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:<1% Appearance and Odor:WHITE OR COLORED FLUID, WITH A PUNGENT SOLVENT ODOR Percent Volatiles by Volume:50 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES FOR SOLVENT: STRONG ALKALIS/OXIDIZERS; ALUMINUM, ZINC AND OTHER REACTIVE METALS (E.G., POTASSIUM, SODIUM, MAGNESIUM). Stability Condition to Avoid:CONTACT WITH OPEN FLAME OR OTHER HIGH TEMPERATURE SOURCE. Hazardous Decomposition Products:THERMAL DEGRADATION, E.G., OPEN FLAME, CAN PRODUCE SMALL AMOUNTS OF PHOSGENE, HYDROGEN CHLORIDE AND CHLORINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE AS REGULAR TRASH. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.